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    һ????????? ?????????????ҵ?????̵IJ??ϼ??SO2??NOX??Ⱦ?ѳ????̳???Ⱦ??Ϊ?????????ĵ?һ????Ⱦ?????????FGD???б???????????ʽ????????Ψһ???ģ??ҵ??Ӧ?õ????򷽷????ǿ????????SO2??Ⱦ????Ϊ??Ч?ĺ???Ҫ?ļ????ֶΡ? Ŀǰ??????????????????򶼷dz????ӣ??ѿ???????ʮ????֮??Ч?????????????й㷺???õ?????????????: (1)ʯ??/ʯ??ʯ—ʪ???? (2)??

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    (3)¯???????ʪ???(LIFAC)??
    (4)??ˮ???????򷨡?
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    (6)????ʪʽ???????һ?廯??????

    ʯ??/ʯ??ʯ—ʯ??ʪ????????????ú?ֿ???ԭ???????׵á??????ʸߣ??ɴ?90%???ϣ???????ŵ㣬ռ???????г??ݶ??Ͷ?ʺ????з??ô?????ά??????
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    ¯?????β????ʪ?????????ʿɴ?70%—80%????????۽ϵ͡?????Ϊ??????ƣ?CaSO3??,?????¯?ڽ?????
    ??ˮ???????????????ռ򵥣?ϵͳ???пɿ????????ʸߣ??ɴ?90%???ϣ????з??õ͡?????ϵͳ??Ҫ?????ں????Һ?ˮ?¶Ƚϵͣ??ܽ?????OC???ϸߡ?
    ????????ͨ???Ժϳɰ?Ϊԭ?ϣ?????Ϊ?򰱵ȡ???Ҫ?ڽ??ϳɰ??????????ʳ???
    ????ʪʽ???????һ?廯???????????ʵͣ?60%???ң?????۽ϵ?ԭ??Ϊ??ҵ?ϼ?ռ??Ҫ?ٽ??зϼ?Һ?ŷŵĹ??????кͺ󣬷?ˮ????????ˮ?????д?????
    ????????ļ?????װ????Ȼ???????ƣ????ڴ???????ң???????????Դ?ṹ??ú̿ռ?ϴ?????Ĺ????У????ƹ???ռ?ȴ?ٲ?Ψ?裬???ҹ???˵????20???????????????ļ?????װ???????ƹ㣬?޶??Ͷ?ʺ͸߰??????з???ʹ??ҵ?????˳??صĸ????????Գ??ܡ?????˵?????????ƹ??ռ?????ļ?????װ?û??д??ڼ????о??Ϳ?????

    ?????ڹ??ʹ????г??????쳣???ҵ??????£?Ҫ?о?????һ???µļ??????豸װ?ã?ʹ???ܴ??ģ?ռ?Ӧ?ã?Ӧ?߱????¼?????????
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    ??ͳ??“ʯ??ʯ—ʯ?෨????????”??Ҫ??ʯ??ʯ??ĥ??200—300Ŀ??????????Ҫ??һ????ĥվ????????Ͷ?ʣ????????һ???̶ȵ?“????”??“?۳?”??Ⱦ??????????뷴Ӧ??????һ????ɸ???ȵ???ߣ??????????з??á????????????????????һ?廯??????????ʵ??????????????ͬʱ??һ??װ??????ɣ??????豸?򵥡?Ͷ??С?????з??õͣ????????߾???Ч?档
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    ʪ??????????????ߣ??ɴ?90%???ϣ????кͲ????????֣??????CaSO4?????????CaSO3??ͨ???????????ʵĻ????кͲ??ﱻ??ȫ?????õĿ????Բ????????????ƣ?CaSO3??һ??????ˮ?壬?????????к?ǿ?Ļ?ԭ?ԣ???Ѹ?ٺľ?ˮ?е??ܽ?????ʹˮ??????????????????????????Ϊ???ܽ??ٶȺ?????????Ⱦ????ںܳ?ʱ???ڴ??ڣ??????ƻ?ˮ????̬???????????кͲ????в?????????ƣ?CaSO3????Ϊ??ȫ???ȿ??????ô????ֵҲ?ɰ?ȫ?ŷš?
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    ????ȣ?Ca/S???Ǿ??????з??õ???Ҫ???أ?Ca/S=1?Ǿ??????еļ???״̬??Ҳ????˵??????????Ca/Sʵ?ֻ?ӽ?1????ô???Ϳ???ʵ??????????ľ??????С?Ŀǰ??ʪ??????ʣ?෴Ӧ???????????????һ???ų????޷????룬???Ժ???ʵ???????Ca/S, ?????Ӧ???Կ???״̬???ڣ??????????⣬ʵ???????Ca/S??Ϊ???ף??????豸???ʽ?Ͷ??Ҳ??֮???٣???????ʵ??????????ľ??????С?

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    ??5??Ͷ???٣????ռ򵥣????з??õ??????޶?????Ⱦ??
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    ??8??????????????????????ȡ?

    ????????ģ??????ܹ?ʵ?֣??ܿ??ܳ?Ϊ??????????????Ϊ?????????ģʽ???????ƹ??Ӧ?ÿ??Դ???޴???г??????????ֵ????Ҫ????ʵ??????????ģʽȴ???ѣ???Ҫԭ???ǣ?
    (1)ʯ??ʯ????ҪѸ???ܽ⣬PHֵ????С??4????PHֵС??4ʱCaCO3???ܽ????SO2?????????ա?
    (2)SO2????ˮ???ɵ?H2SO3???????????ɵ?H2SO4????ʯ??ʯ??????Ӧ?????ɵ?CaSO3??CaSO4?ḽ????ʯ??ʯ?????ı??棬????Խ??Ӧ?ѻ?Խ?࣬ʹ??Ӧ???Ѽ?????????ȥ??
    ??3??CaSO4??CaSO3ͬΪ???ղ??ʹCaSO4?????Ҳ?????CaSO3?DZȽ????ѵġ?
    ????˵??3????????“ʯ??ʯ??”?????????????????Խ?????գ??ܷ?????3????????????????ܷ?ﵽԤ??Ŀ?꼰??װ???ܷ??ȶ????еĹؼ??? 

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    ??Ȼ?????վ?Ӧ?ü???һ????????????Խ??ȥ?????о?????????????????һ?廯???????м??????á?????????????һ?廯??????ϵ??????????????????????????????ͨ????ˮ????????ö???????ԭ??????????ˮ?У??ھ????ܽ????н???????ˮ???г?ֵؾ??ȵػ?Ϻ??ܽ⣬?Ӷ?ʹ?????еķɻҺͿ?????ˮ??ʪ?????????к?????????ˮ?У????û?ѧ????????????е?SO2??NOX?ͷ۳??????ַ?????ͨ????ͼ??ʾ?Ĺ???ԭ??ͼ??ʵ?ֵġ????ij???Ч??100%??????Ч??>98%??????Ч??>90%???ϡ??????????????ͬʱ????һ̨???????????????ȼú(??????)??¯?????ֹ?ҵҤ¯?ȵ????????????????̡?ϵͳ?ṹ?򵥣??ɱ??ͣ????ܼ۸?ȸߣ????ܣ??͸??£?????????


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    ????Ч??100%??????Ч??>97%??????Ч??>90%???ϡ??????????ֳ???ˮ?೧?ȹ?ҵҤ¯???͸???????????
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    ǰ?????ڸɷ??????????????????ȣ???ȥ>90%?ķ۳??????ڻ??????ã??󼶲???????????????һ?廯????????????????????Ч??100%??????Ч??>97%,????Ч??>90%???ϣ?????SO2ת??Ϊʯ?ࡣ
    1??ʯ?෨?Ĺ???????ͼ


    2????ѧ??Ӧ????ʽ????
    Ca(OH)2+SO2=CaSO3+H2O
    2CaSO3+O2=2CaSO4
    CaSO3+1/2H2O=CaSO3•1/2H20
    CaSO4+2H2O=CaSO4•2H2O
    CaSO3•1/2H20+O2+2H2O=2CaSO4•2H2O
    NO+NO2+H2O+O2=2HNO3
    Ca(OH)2+2HNO3=Ca(NO3)2+H2O

    ???????ջ??ʷ?(??-??????立?)???÷?Χ
    ?????ڸ??ֹ???ȼú???͡???????¯??ȼú?к??????󣻲???????????????һ?廯????????Ч??100%??????Ч??>98%??????Ч??90%???????̡?????????ˮ?????̼??????????ռ???

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    2NH4HCO3+SO2=(NH4)2SO3+H2O+2CO2    (A)
    (NH4)2SO3+SO2+H2O=2NH4HSO3         (B)
    ???չ????ԣ?B??ʽΪ??????2NH4HSO3?ڲ?????????ֻ?Dz???????ϵͳʹ????2NH4HSO3????Ϊ(NH4)2SO3???Ա???ѭ??????Һ??ȣ?SO2/NH3?????????䡣
    ????????????????(NH4)2SO3+O2/2=(NH4)2SO4??ͨ???????к???????SO3?????У?
    NH4HCO3+SO2+H2O=(NH4)2SO4+ NH4HSO3??NH4HSO3?????ԡ???ӹ???̼??????кͺ?ʹNH4HSO3ת??Ϊ(NH4)2SO4??
    NH4HSO3+ NH4HCO3= NH4HSO3•H2O+CO2      ??C??
    ??C??ʽΪ???ȷ?Ӧ????Һ??????ȴ???ɽ???0?????ҡ?????(NH4)2SO3??NH4HSO3??ˮ?е??ܽ?ȴ?????Һ??NH4HSO3•H2O?????ͽᾧ????????????Һ?????ķ?????Ƶù?????????

    ?ߡ?????????????˵??
    1????Ϊ????????ν??????ָ???dz?ȥ?????е?NOX??NOX??Ҫ??NO??NO2??ɣ???NO????ռ90%???ϡ?Ҫ??ȥ?????е?NO??NO2???ͱ????о?NO??NO2?????ʡ?
    NO??һ?ֶ????????????Ȼ????ˮ???????????ɵ??ĺ????ᡣ??0??ʱ??һ???ˮ???ܽ?0.07?????NO??NO??????Ļ?ѧ?????ǼӺ????ã??ڳ?????????????е??????ϣ????ɺ???ɫ??NO2??NO?Dz??ȶ??ģ???O2????????ʹO2???ѳ???ԭ?ӣ????????е?һ????ԭ?ӽ?ϳ?NO2??
    NO2?Ǻ???ɫ???????ζ?????壬??-10?????Ҿۺϳ?N2O4????120??ʱN2O4ȫ???ֽ??NO2???¶??ٸ?NO2??ʼ?ֽ??NO??O2??NO2??һ??ǿ???????????ܰ?SO2??????SO3??NO2????ˮ??????????????ᡣNO2?Ķ?????NO??5????

    NO??NO2?????????????أ?һ???????N2??O2?????????Ϸ?Ӧ???????????????ڿ????зŵ?ʱ???ڸ???ȼ?չ????в????ģ?????????NO??Ȼ????NO??????NO2???ڸ???ȼ?չ????п????еĵ???ȼ???еĵ?????Ȳ?????ȼ?յ???????????ѧ??Ӧ???????γ?NO?????????һ???????̵????????????γ?NO2,?󲿷ֵ?NO???̴????????????????????е?????ϳ?NO2????δ????????NO2??NO???ڴ???????NO2??????????
    ??ȼ?չ?????ȼ???????¶?Խ?ߣ???ʣ????Խ?࣬?γ?NO????Խ?ࡣ????ȼ??Ч??Խ?ߵ?????£?NOԽ???????ɡ?????ȼ?շ?ʽ???ɵ?NOX??NOռ90%???ϣ?NO2???١?
    ???ճ??õ?ȼ?շ?ʽ??ú??ȼ??????NOX?ĺ???Ϊ500-1500ppm??

    2??ʪ??????
    ??????????Ϊ?ɷ???ʪ?????֡??ɷ?????Ч????80%???ң??ҳɱ??ϸߡ????????ʪ????????
    NO2????ˮ?????????NO??
    3NO2+H2O=2HNO3+NO
    ???????㹻ʱ??
    4NO2+O2+2H2O=4HNO3
    NO??Ȼ????ˮ???????????ɵ??ĺ????ᡣ??0??ʱ??һ???ˮ???ܽ?0.07?????NO??NO??????ˮ??Ϊ???????ѵ㡣????“????????????һ?廯????”?????㹻??ˮʹNO????ˮ?У??й??о???????ˮ??Һ?????Ậ??>12%ʱ??NO???ܽ?ȱ??ڴ?ˮ?д?100??????һ???ˮ???ܽ?7?????NO??????????ʼ????ˮ??ʱˮ?Ǵ???????????NO2????ˮ??????HNO3?????NO2??ˮ?в?????ԭ??????“????????????һ?廯????”????ˮ?ı??????㣬2Сʱ44???Ӻ?ˮ??Һ??????ĺ?????Ϊ12%???ҡ???˿???˵NO????ˮ???Dz???????ġ?

    NO??NO2??Ȼ????????ˮ?С????û?ԭ???????ǻ?ԭ??N2??????ԭ??ʹ?õĻ?ԭ??Ϊ(NH4)2SO3??NH4HSO3?????????ǰ??????????еIJ????ԭ??????????Һ?У????????Ѿ??ھ????ܽ????????ĵؽ????š???ΪNOX???????е?????????С????ԭ??(NH4)2SO3??NH4HSO3?????????㹻?ġ????NOX??????????ȫ??????ԭ??ʣ??IJ??ֽ????NH4NO3????????Һ?к?(NH4)2SO4һ?𱻴???Һ?з????????Ϊ???ʡ????ǻ?ѧ??Ӧ????ʽΪ??
    2NO+O2=2NO2+27ǧ??
    NO+NO2+H2O=4HNO2
    NO2+2H2O=HNO2+HNO3
    4NO2+O2+2H2O=4HNO3
    NH3+HNO3=NH4NO3
    NH3+HNO2=N2+2H2O
    NH4OH+HNO3=NH4NO3+H2O
    NH4OH+HNO2=N2+3H2O

    NO+NO2+3(NH4)2SO3=N2+3(NH4)2SO4

    NO+NO2+3NH4HSO3=N2+3NH4HSO4

    4NO2+H2O+3(NH4)2SO3=N2+3??NH4??2SO4+2HNO3

    4NO2+H2O+3NH4HSO3=N2+3NH4HSO4+2HNO3


    NH4OH+NH4HSO4=(NH4)2SO4•H2O
    3??????????????Ч??
    1???????ʣ?98%
    2???????ʣ?90%
    3??????Ч?ʣ?100%

    ?ˡ??????????ص?

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    ??8???????????????ȵ????պ????á?
    ??9??????ɣ?ˮ?塢???????۳??ȣ???????Ⱦ??
    (10)??????????????ͬһ??װ??????ɡ?һ????Ͷ?ʣ???????98%????????90%???ϣ???????100%?????ɽ??д???ŷš?
    ??11?????з??õ͡??ȴ?ͳ???򷽷????????з???50%-80%???ҡ?

    ?š????????򽵵ͷ???
    Ŀǰ?????????????????????????Ǽ??????ӣ???۸ߣ????з??ô?һ̨300MW??30??ǧ?ߣ????????????????һ????ñȽϳ????ʯ??ʯ--ʯ??ʪ??????????????Ч??95%???ң?ÿ????ٶ????????ŷ???Լ1??֣?ÿ?ѳ?1??ֶ????????????????Ͷ??Լ1??1.5??Ԫ???糧??????????ʩ?????кĵ????ϴ?һ???????????õ???˹??????з???1600??Ԫ???ң?̯??ÿ?ȵ?????????Լ0.03Ԫ??????????۵???????ֻ??0.015Ԫ????ʱ??ʮ?ֵĹ?¯??????˫????????ռ????????????????????ۼ۳ɱ???ߣ????????з?????֮????????ߡ???ú??????50%??;?????????˫??ѹ???£???????????ȱ?ڴ󣬸߳ɱ?????????ʩ?ܷ????????????????Ͼ??Ŀ??顣

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